It seems like most of the 2.0 engines in colder climates experience a buildup of a gooey yellow or brownish substance under the oil cap in the winter. Wiping it up with a paper towel shows that it is actually mostly water. It is created by the combination of oil vapors and water condensation in colder portions of the crankcase volume.
I believe that the root cause is the inadequate design of the crankcase ventilation system for this engine. Every other car I have owned used a pair of crankcase ventilation hoses; one between the valve cover and the air filter box to supply clean air to the crankcase and another from the valve cover to the PCV valve. Air is drawn out of the crankcase through the PCV valve and into the intake manifold. Since there are both an air inlet and a vacuum source, a constant flow of air takes place.
With the 2.0 engine there is a single ventilation hose and there is no conventional PCV valve. The single hose runs from the vent housing under the oil cap to the air intake boot near the inlet to the throttle body. At the air intake boot there is a reed valve that allows flow in one direction: out of the crankcase and into the intake boot. The reed valve in combination with the natural air pulses at the throttle body will create some vacuum, similar what is provided by a PCV valve. However, without a way for air to get into the crankcase the only air flow in the crankcase comes from the blow-by combustion gases that get past the piston rings. Water vapor is a major combustion byproduct, so not only is there very small airflow through the crankcase, but what there is contains a lot of water vapor. As a result there is a lot of condensation at the coldest point in the crankcase volume, which is the vent housing and ventilation hose.
So, it looks like we will have to live with the yellow goo. Does it do any harm? Well I found that my ventilation hose was completely plugged with the goo. In fact, if there is much goo visible under the oil cap then it is likely the ventilation hose is plugged. After I cleared out the ventilation system I found that an oil leak that I had assumed was from the rear main oil seal completely stopped! The plugged hose allowed pressure to build up in the crankcase which pushed oil out the main seal or perhaps the vent housing/valve cover joint and then down the back of the engine. An overpressurized crankcase can cause driveability problems as well.
Here is a DIY that I put together on how to clean out the goo:
1. Remove the engine cover using a 10 mm wrench. Here is a photo of the ventilation system components that you will find underneath:
A - Vent housing.
B - Ventilation hose.
C - Intake boot.
D - Reed valve housing.
2. Use pliers to squeeze the clamp securing the ventilation hose to the reed valve housing and slide it down the hose. Remove the end of the hose from the reed valve housing.
3. Twist the vent housing clockwise about 45° and lift it up to remove from the valve cover. It attaches like an oil cap, but twists in the reverse direction. Here is a photo of the assembly about to be removed from the valve cover:
4. Remove the oil cap, clamp and hose from the vent housing. If you had any amount of goo visible under the oil cap the chances are the ventilation hose will be completely full with it. Here is a photo of the disassembled parts:
5. Clean the goo out of the vent housing and the ventilation hose by gently tapping them on a piece of cardboard or newspaper. The goo, being partly oil, is very slippery and easily comes out just with tapping.
6. Inspect the hose to make sure it isn't cracked or damaged. If it needs to be replaced I recommend a genuine VW part as the aftermarket ones tend to be made of really cheap material and don't last.
7. Reassemble in reverse order.
The procedure may need to be repeated every few weeks during cold weather. The condition of the ventilation system can be monitored simply by removing the oil cap and inspecting for a buildup of the goo.